On March 11, 2016, Arrow was renewed for a fifth season by The CW. It premiered on October 5, 2016. It took place in conjunction with the third season of The Flash, the second season of Supergirl and the second season of DC's Legends of Tomorrow.
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| 1 | "Legacy" |
| 2 | "The Recruits" |
| 3 | "A Matter of Trust" |
| 4 | "Penance" |
| 5 | "Human Target" |
| 6 | "So It Begins" |
| 7 | "Vigilante" |
| 8 | "Invasion!" |
| 9 | "What We Leave Behind" |
| 10 | "Who Are You?" |
| 11 | "Second Chances" |
| 12 | "Bratva" |
| 13 | "Spectre of the Gun" |
| 14 | "The Sin-Eater" |
| 15 | "Fighting Fire With Fire" |
| 16 | "Checkmate" |
| 17 | "Kapiushon" |
| 18 | "Disbanded" |
| 19 | "Dangerous Liaisons |
| 20 | "Underneath" |
| 21 | "Honor Thy Fathers" |
| 22 | "Missing" |
| 23 | "Lian Yu" |